3-D characterization of carbon nanotube-polymer composites using scanning electron microscopy and confocal Raman microscopy

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3D characterization of the dispersion of CNTs in a polymer matrix is a critical step toward understanding and improving the performance of CNT polymer composites. In this study, SEM and confocal Raman microscopy (CRM) were employed for this purpose. First, non-destructive subsurface imaging of a CNT-polymer composite was conducted through charge-contrast SEM imaging. Figure 1 shows a 3D reconstruction of SEM images, capable of elucidating the structure to a depth of several hundred nanometers. Second, we demonstrated high-throughput and depth-accurate 3D characterization of CNT polymer composites, by optimizing CRM parameters and the use of high-numerical aperture immersion lenses. This allowed for characterization of the dispersion of CNTs, from the near-surface region to approximately 30 microns below the surface (Figure 2). While this is two orders of magnitude deeper than possible with SEM, the spatial resolution of charge-contrast SEM is about an order of magnitude greater than that of CRM, making the two techniques complementary. Finally, these techniques can be used to characterize nanostructures embedded in either a low-dielectric constant matrix by charge contrast SEM or a transparent matrix by CRM, with applications ranging from semiconductor overlay imaging to toxicity studies of nanoparticles swallowed by cells.

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Journal: TechConnect Briefs
Volume: 1, Nanotechnology 2014: Graphene, CNTs, Particles, Films & Composites
Published: June 15, 2014
Pages: 33 - 36
Industry sector: Advanced Materials & Manufacturing
Topicss: Carbon Nano Structures & Devices, Graphene & 2D-Materials
ISBN: 978-1-4822-5826-4