We have developed asymmetric carbon nanotube/polyamide membranes for desalination applications. The carbon nanotubes are functionalized with zwitterionic groups that control the rejection of anionic species, while permitting the transport of water. Water flux measurements demonstrate that the water flux in the CNT-nanocomposite membranes is orders of magnitude higher than that observed in an asymmetric polyamide membrane, with salt rejection maintained above 80%. We have also conducted corresponding atomistic simulations of the water and ionic transport. We used non-equilibrium molecular dynamics to model the transport of fluids through functionalized carbon nanotubes, including entrance effects. We have shown that zwitterions are able to completely block the flow of salt ions while still allowing water flux through the membrane.
Journal: TechConnect Briefs
Volume: 3, Nanotechnology 2012: Bio Sensors, Instruments, Medical, Environment and Energy (Volume 3)
Published: June 18, 2012
Pages: 684 - 686
Industry sectors: Advanced Materials & Manufacturing | Energy & Sustainability
Topicss: Materials for Sustainable Building, Sustainable Materials