Chemoselective Hydrogenolysis of Glycerol Catalyzed by Platinum on Carbonaceous Supports

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Glycerol has been selectively converted into 1,2-propandiol in the presence of dihydrogen and heterogeneous Pt-based catalysts. These latter catalysts consist of small-size Pt-nanoparticles (NPs) (i.e. 1.0-1.5 nm,) obtained by a metal vapor synthesis, supported on different carbonaceous supports which differ mainly in surface area and surface polarity. Catalytic data combined with microscopic (i.e. TEM investigations of the supported Pt-NPs after catalysis) evidences showed a good correlation between the catalytic activity and chemoselectivity of the Pt-NPs and the NP-stabilizing property of the carbonaceous supports.

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Journal: TechConnect Briefs
Volume: 3, Nanotechnology 2014: Electronics, Manufacturing, Environment, Energy & Water
Published: June 15, 2014
Pages: 273 - 276
Industry sectors: Advanced Materials & Manufacturing | Energy & Sustainability
Topics: Catalysis
ISBN: 978-1-4822-5830-1