Atmospheric Plasma Surface Modification of Polytetrafluoroethylene Films for Metal Deposition

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This work details the use of atmospheric-pressure dielectric barrier discharge plasmas to enhance the adhesion of thin metal coatings to PTFE films. Differences in energetic plasma species have a pronounced effect on resulting wettability. Increased exposure to energetic oxygen ions in a He-O2 plasma leads to an increase in water contact angle, indicating either a chemical restructuring of the PTFE surface, and/or the creation of a smoother surface. Our initial results show a maximum decrease in water contact angle of approximately 21° after only 10 seconds of He-O2 plasma exposure. Scanning electron microscopy imaging performed on plasma-treated surfaces reveal changes in morphology, indicating physical etching and roughness changes caused by the plasma. A comprehensive study is also planned to observe the effect of various plasma parameters on surface energy; such as gas flow rate and composition, power output, and the effects of any evaporated monomer precursors. Additionally, a T-peel type test will be used to evaluate the strength of the polymer/metal interface. This test will also be used to quantify the extent of metal removal during testing.

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Journal: TechConnect Briefs
Volume: 1, Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites
Published: June 21, 2010
Pages: 677 - 680
Industry sector: Advanced Materials & Manufacturing
Topics: Advanced Materials for Engineering Applications, Coatings, Surfaces & Membranes
ISBN: 978-1-4398-3401-5